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Color-stable water-dispersed cesium lead halide perovskite nanocrystals

机译:颜色稳定的水分散卤化铯铅钙钛矿纳米晶体

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摘要

Cesium lead halide perovskite nanocrystals are being lately explored for optoelectronic applications due to their emission tunability, high photoluminescence quantum yields, and narrow emission bands. Nevertheless, their incompatibility with polar solvents and composition homogenization driven by a fast anion-exchange are still important drawbacks to overcome. Herein we report on a successful encapsulation of colloidal perovskite nanocrystals within solid–lipid structures mainly consisting of stearic acid. The product is water-stable for a period longer than 2 months and anion-exchange is fully arrested when mixing nanocrystals of different halide compositions. This strategy boosts the potential applications of all-inorganic perovskite nanocrystals for ink-printing.
机译:卤化铯铅钙钛矿纳米晶体由于其发射可调性,高光致发光量子产率和窄发射带而正在近来被探索用于光电应用。然而,它们与极性溶剂的不相容性和由快速阴离子交换驱动的组成均质化仍然是要克服的重要缺点。在这里,我们报道了在主要由硬脂酸组成的固体-脂质结构中成功包裹胶体钙钛矿纳米晶体。该产品的水稳定性超过2个月,混合不同卤化物组成的纳米晶体时,阴离子交换被完全阻止。该策略促进了全无机钙钛矿纳米晶体在油墨印刷中的潜在应用。

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